Battery Encyclopedia
Everything you want to know about batteries from A to Z, curated by TWAICE experts.

Regulation involves the implementation of laws and guidelines governing the production, usage, and disposal of batteries. These rules ensure safety, environmental protection, and fair market practices. For example, the European Union's Battery Directive mandates specific recycling rates for battery materials and requires manufacturers to comply with labeling and performance standards to reduce environmental impact and enhance consumer safety. In the United States, the Battery Act (Battery Management and Recovery Act) sets forth guidelines for battery recycling and disposal, aiming to minimize environmental hazards and promote the safe handling of batteries throughout their lifecycle.
Relaxation time refers to the period a battery needs to reach a stable voltage and temperature after charging or discharging. Understanding relaxation times is crucial for accurate state of charge and state of health estimations.
In the context of batteries and energy systems, reliability refers to the ability of the system to perform its required functions under expected conditions over a specified period. It's a critical factor in applications like power grids, electric vehicles, and portable electronics.
The remaining energy capacity in a battery, indicating how much more charge can be stored. Knowing the residual capacity is important for managing energy usage, planning recharges, and avoiding unexpected power loss. It also plays a key role in determining the end-of-life of a battery when its capacity falls below a certain threshold of its original capacity.
The duration for which a battery or system can operate on a single charge under specified conditions.
SCADA (Supervisory Control and Data Acquisition) is an industrial automation software system that enables centralized monitoring, real-time data acquisition, and remote control of infrastructure assets.
A SCADA system typically includes human-machine interfaces (HMIs), programmable logic controllers (PLCs), sensors, and communication protocols that ensure secure and reliable data flow between devices and operators.
Refers to the range within which the State of health (SoH) of a battery can be expected to lie with a certain confidence. It provides a statistical measure of the uncertainty or variability of the SOH estimation.
The voltage range within which a battery or device can operate safely, without risk of damage or unsafe conditions.
This concept involves repurposing used batteries (often from electric vehicles) for new applications, typically less demanding than their original use. For example, EV batteries that have degraded below an acceptable level for vehicle use might still be suitable for stationary energy storage applications.
Self-discharge is the loss of stored energy in a battery when not in use. All batteries exhibit self-discharge to some extent, but lithium-ion batteries generally have a lower self-discharge rate compared to other storage technologies. Minimizing self-discharge can help prolong battery life and maintain optimal performance.
The separator is a critical component in lithium-ion batteries, providing a physical barrier between the anode and cathode to prevent short circuits while allowing lithium ions to passthrough. Separators are typically made from porous materials like polyethylene or polypropylene.
The Single Electricity Market (SEM) is a unified wholesale electricity market that allows multiple jurisdictions to trade electricity across borders under a common regulatory and operational framework. A notable example is the SEM between Ireland and Northern Ireland, where generators and suppliers operate under a single balancing and settlement system. SEMs improve grid efficiency, enhance competition, and support renewable energy integration
A charging method for batteries that uses lower current over a longer period, often to preserve battery health and extend lifespan.
The process of estimating the State of Charge of a battery, indicating the current energy level relative to its maximum capacity. Accurate SoC estimation allows for the optimal operation of battery systems, preventing overcharging or deep discharging that can harm battery life. Techniques for SoC estimation range from simple voltage-based methods to more complex algorithms that incorporate multiple variables and historical data.
Sodium layered oxides are a class of materials characterized by their layered crystal structure, where sodium (Na) ions are intercalated between layers of metal oxides. The "layered" aspect refers to the stacking of alternating layers of sodium ions and transition metal oxides, which often results in a two-dimensional structure. Sodium layered oxides are of particular interest in the field of energy storage, particularly for use in sodium-ion batteries, due to their ability to reversibly intercalate and de-intercalate sodium ions during charge and discharge cycles. The properties of these materials, such as capacity, stability, and conductivity, can be tuned by varying the type of transition metal and the amount of sodium in the structure.
These are a type of rechargeable battery that uses sodium ions as the charge carrier. Sodium-ion batteries are attractive due to the abundance and low cost of sodium compared to lithium, making them a potentially more sustainable and cost-effective option for large-scale energy storage.
A layer that forms on the electrode/electrolyte interface (on the anode surface) of a lithium-ion battery during the initial charging cycles. While it helps stabilize the battery's operation, its growth also leads to capacity loss and resistance increase over time.
Solid-state batteries are an emerging technology that replaces the liquid electrolyte and the separator in conventional lithium-ion batteries with a solid electrolyte. They offer increased energy density, enhanced safety due to reduced risk of thermal runaway, and improved cycle life. However, solid-state batteries face challenges related to manufacturing, scalability, and cost. In the ideal case, the use of solid-state electrolytes enables the use of anode-free cell configurations, meaning there is no anode available during the manufacturing process, but it is created each discharge process in the form of a thin metallic lithium layer on the anode current collector.
These are algorithms used in battery management systems (BMS) to estimate important battery parameters that cannot be measured by the BMS, like state of charge and state of health. Kalman filters, for example, use a series of measurements observed over time, containing statistical noise and other inaccuracies, and produce estimates of unknown variables that tend to be more precise than those based on a single measurement alone.
In simple terms, the State of Charge (SoC) provides information on how much charge is still available in the battery. In an ideal case, the SoC can be determined by measuring the charge drawn from and pushed back into the battery. A challenge arises since measurements are not fully precise, meaning the measurement of charge out and charge in might be different, just because sensors are not capable enough to count every change of charge. Also, not every charge which is inserted into the battery will be available later on to leave the battery again, since some processes inside consume charge via side reactions. Hence, the SoC needs to be determined by other means, not only by measuring charge in and out, but also by checking the resulting voltage.
The voltage measured outside at the battery is the difference between the cathode and anode potential. The cathode and anode potential is determined by the amount of lithium ions stored within the material. Therefore, one way would be to use a look-up table to check which voltage level corresponds to the amount of lithium ions stored in the battery electrodes, which then can be used to determine the SoC. However, the voltage itself is also affected by temperature and age of the battery. Other effects such as polarizations make the SoC determination only by voltage readings challenging as well.
It is generally defined as the ratio of the current capacity to the initial capacity. SoH is generally defined with capacities (SOHc). However, SoH can also be defined in terms of resistance increase (SOHr) or it can be based on the available energy compared to the initial energy (SOHe). It is also seen that SoH is sometimes scaled between 0 and 1, where 1 is a new cell and 0 is when the cell reaches the End of Life criteria (e.g. 80% remaining capacity).
SoH is a challenging KPI. Firstly, there is often no attention paid to the right framing of the SoH. Since the value is a result based on the division of two values, we need to ensure that both values are actually comparable. That means, the available capacity needs to be determined under the same conditions as the initial capacity. Concretely that means, that i.e. voltage or State of charge limits need to be the same. Otherwise, the available and initial capacity represent different states and are not comparable.
Secondly, the available capacity, energy or resistance needs to be determined during the everyday operation, which follows dynamic and uncontrolled patterns. Additionally, temperature and the operation history influence the available capacity, energy and resistance but their influence must be compensated to determine the actual available state. Therefore, sophisticated models and algorithms are needed to ensure accurate results even with noisy and uncontrolled field data.
This refers to the calculation of the value below which a certain percentage of observations in a dataset fall. For example, the 50th percentile (median) is the value below which 50% of the observations may be found. Percentile computation is widely used to understand the distribution and tendencies in a dataset, such as understanding the performance benchmarks in battery lifecycles or energy consumption patterns.
An energy storage device that offers high power density and rapid charging/discharging capabilities, complementing or replacing batteries in some applications.
Sustainability in batteries involves creating and managing battery systems in ways that minimize environmental impact and promote long-term ecological balance. This includes using eco-friendly materials, efficient production methods, and effective recycling processes.
A theoretical framework used to understand and predict the forces exerted by swelling of battery components during operation.
The physical expansion pressure exerted by gases or electrolytes within a battery cell. This can be caused by internal reactions, especially in faulty or damaged cells, leading to the physical swelling of the battery.
System design in the context of battery technology involves planning and configuring the entire battery system to meet specific performance and application requirements. It includes selecting appropriate components, defining system architecture, and ensuring compatibility, safety, and efficiency throughout the battery's lifecycle.
This term refers to periods when a system, such as a power plant or a battery storage facility, is not operational. Downtime can be scheduled (for maintenance) or unscheduled (due to failures or external factors). Minimizing downtime is crucial for maximizing efficiency and reliability.
The minimum and maximum temperatures within which a battery can safely operate, maintaining performance and longevity.
A thermal model mimics the thermal response of a battery cell to an applied load. The thermal behavior is the response due to the reversible and irreversible generation of heat. Irreversible heat generation is driven by effects such as Joule heating and internal, chemical side reactions. Reversible heat is created by the entropy changes of the respective materials during electrochemical reactions.
This phenomenon in battery systems refers to the spread of excessive heat from one part of the battery to another. It can be particularly dangerous in large battery packs, as heat from one overheating cell can propagate to adjacent cells, potentially leading to thermal runaway, where the temperature keeps increasing uncontrollably.
Thermal runaway is a dangerous condition in which a battery's temperature rapidly increases due to an uncontrollable exothermic reaction (that means reactions create heat, which trigger further reactions which themselves, create even more heat), leading to the release of toxic gases, fire, or explosion. Factors leading and contributing to thermal runaway include internal short circuits, overcharging, excessive heat, and mechanical damage.
Titanium is often used in the anode of lithium-titanate (Li₄Ti₅O₁₂ or LTO) batteries, where it provides fast charging, excellent cycle stability, and enhanced safety. Titanium can also be found in certain cathode materials, contributing to stability and safety, though it typically results in lower energy density compared to other materials.
This phenomenon occurs in some lithium-ion batteries, where transition metals from the cathode material (like nickel, manganese, or cobalt) dissolve into the electrolyte. This process can be accelerated by factors like high temperature or overcharging. The dissolved metals can then deposit on the anode, leading to a decrease in capacity and battery life.
A Transmission System Operator (TSO) is an entity responsible for operating, maintaining, and developing the high-voltage electricity transmission grid. TSOs ensure the reliable and secure flow of electricity from generation sources to distribution networks or large industrial consumers. They play a vital role in balancing supply and demand, facilitating cross-border energy exchanges, and integrating renewable energy into the grid. TSOs are regulated to maintain transparency, neutrality, and grid stability across national and regional power markets.
UL 1741 defines safety standards for power conversion and interconnection equipment used in distributed energy resources (DERs), including energy storage systems. In BESS applications, it ensures that inverters and control systems operate safely, especially during grid-tied operation. When combined with IEEE 1547 and tested under UL 1741 SA/CRD protocols, it supports grid interoperability and anti-islanding functions.
UL 1973 is a product safety standard specifically for batteries used in stationary applications, including BESS. It evaluates the safety of battery modules and systems under normal and fault conditions, covering electrical, mechanical, and environmental performance. Certification to UL 1973 is often required by authorities having jurisdiction (AHJs) for permitting and code compliance.
A condition where the voltage of a battery falls below the minimum threshold needed for operation, potentially leading to reduced performance or damage. Operating a battery under undervoltage conditions can lead to irreversible damage and decreased battery capacity.
Usable energy is the portion of total energy a system is currently capable of delivering, expressed in megawatt-hours (MWh) and as a percentage of its original capacity. It captures the system’s present performance, accounting for factors like irreversible aging, the presence of weak or degraded cells, imbalances in state of charge, and offline components. As such, it represents both the energy available now and the margin that could potentially be recovered through corrective actions.
Volatility in the context of renewable energy refers to the rapid and unpredictable fluctuations in energy generation and supply. Effective battery systems help mitigate this volatility by storing excess energy during peak production times and releasing it during periods of low generation, ensuring a stable and reliable power supply
Voltage, often measured in volts (V), is the electrical potential difference between two points in a circuit. It's analogous to the pressure in a water pipe, pushing electrons through a conductor. In batteries, it determines how much electrical energy can be stored and delivered.
The maximum or minimum voltage to which a battery or cell can be safely charged or discharged.
In a battery module with multiple cells, the voltage spread refers to the difference in voltage levels among the cells. Uneven voltage spreads can indicate issues like cell imbalances and can affect the overall performance and health of the battery pack.
WECC (Western Electricity Coordinating Council) refers to a regional organization responsible for coordinating the reliability and security of the electric grid in the Western Interconnection of North America. This region covers the western parts of the United States, Canada, and a portion of Mexico. WECC's primary role is to ensure the reliable operation of the interconnected power system, develop and enforce reliability standards, and facilitate coordination among utilities and grid operators within its region.
Wholesale trading in energy markets involves the large-scale buying and selling of electricity between generators, retailers, and large consumers before it reaches end users. Trading typically occurs through power exchanges, bilateral contracts, and over-the-counter (OTC) markets. Wholesale energy markets are essential for price discovery, liquidity, and grid planning, often operating on day-ahead and intraday timeframe