impedance of lithium-ion batteries research paper
Research Papers

Impedance Research Paper

Continuous impedance monitoring provides significant insights into the aging status of a battery. However, the on-line determination of battery impedance parameter for its low-frequency part is a challenging task. This paper provides an algorithm for its determination, which features a novel approach to quantifying the impedance caused by diffusion processes at low frequencies.

TWAICE / Nov 23, 2020

twaicetech

TWAICE helped me to learn more about: Impedance Research Paper read article here:

www.twaice.com/research/impedance-research-paper

#thinktwaice

Novel method for the on-line estimation of low-frequency impedance of lithium-ion batteries

Highlights

- Impedance estimation with separate algorithm for high- and low-frequency processes.

- Theoretical background to observable frequencies of impedance in real cycling data.

- Algorithm is based on identification windows, and operates non-recursively.

- Voltage error for commercial 18650 NCA cell below 10mV during the validation cycle.

Abstract

Impedance is an important characteristic of lithium-ion batteries since it directly influences their power capability. However, battery impedance is highly dependent on the operating condition and increases over the lifetime of the battery, due to degradation of the latter. Continuous tracking of the impedance can hence provide meaningful insights into the aging status of a battery. However, the on-line determination of battery impedance parameters, especially for its low-frequency part, is a challenging task, which has not yet been solved unambiguously in literature.

This work provides an algorithm for the on-line determination of battery impedance, which features a novel approach to quantifying the impedance caused by diffusion processes at low frequencies.

The algorithm works by parameterizing an equivalent circuit model comprised of RC elements, which reproduces the Li-ion kinetics. The on-line functionality is enabled by parameterizing the model during parameter identification windows of battery operating data, which allow for the separation of high-frequency and low-frequency dynamics. The developed algorithm is designed in such a way that it can in future be embedded into a low-cost microcontroller by taking into account the relevant computational and memory limitations. During experimental validation with a commercial Li-ion battery, the root-mean-square error of the simulated voltage during diverse static and dynamic loads is reduced by over 50% compared to a benchmark algorithm without the proposed approach.

Access the paper here.

Related Resources

April 12, 2023

Measurement Approaches for Thermal Impedance Spectroscopy of Li-ion Batteries

Battery performance, lifetime and safety are highly dependent on temperature. With the recent high demand for power capabilities, heat management has become increasingly relevant.
February 14, 2023

Evaluation of transmission losses of various battery electric vehicles

Transmission losses in battery electric vehicles have compared to internal combustion engine powertrains a larger share in the total energy consumption and play therefore a major role. In this paper, three simulation models of the Institute of Automotive Engineering are presented.
July 13, 2022

Modeling capacity fade of li-ion batteries

Aging models are fundamental tools to optimize the application of lithium-ion batteries. In this work, we show that the CAP-method models capacity fade more accurately when applied to dynamic cyclic aging tests with periodically changing mean state-of-charge, depth-of-discharge, ambient temperature and discharge rates for a commercial NCA cell with a silicon-doped graphite anode.