Battery material
Research Papers

Non-destructive electrode potential and open-circuit voltage aging estimation for lithium-ion batteries

In this publication we extend a state-of-the-art electrode open circuit potential model for blend electrodes and inhomogeneous lithiation. We introduce a bi-level optimization algorithm to estimate the open parameters of the electrode model using measurements conducted on the full-cell level with state-of-the-art testing equipment.

from TWAICE
Download the content

twaicetech

TWAICE helped me to learn more about: Non-destructive electrode potential and open-circuit voltage aging estimation for lithium-ion batteries read article here:

www.twaice.com/research/non-destructive-electrode-potential-and-open-circuit-voltage-aging-estimation-for-lithium-ion-batteries

#thinktwaice

Non-destructive electrode potential and open-circuit voltage aging estimation for lithium-ion batteries

Authors: Cedric Kirst, Alexander Karger, Jan Singer, Andreas Jossen

‍

Highlights

  • Physical motivated model for blend electrodes and inhomogeneous lithiation
  • Non-destructive estimation of electrode potential curves
  • Validation on commercial LFP-C, NMC-SiC and NCA-SiC Li-ion cells
  • Novel non-destructive degradation mode analysis
  • Achievement of model-based fitting voltage RMSE < 6 mV over lifetime

‍

In this publication we extend a state-of-the-art electrode open circuit potential model for blend electrodes and inhomogeneous lithiation. We introduce a bi-level optimization algorithm to estimate the open parameters of the electrode model using measurements conducted on the full-cell level with state-of-the-art testing equipment.

As input for the optimization algorithm, we use data from a pseudo open-circuit voltage aging study to estimate the electrode potential curves, the electrode capacities, and the capacity of cyclable lithium over lifetime without opening the cell. We validate our method against measurements on commercial lithium-ion cells with the electrode materials LFP-C, NMC-SiC and NCA-SiC, and compare the estimated electrode pseudo open-circuit potential curves to measurements conducted on harvested half-cells.

We conclude that the presented non-destructive method of half-cell open-circuit potential modeling offers an alternative to complex cell disassembly and electrode material harvesting for degradation mode analysis.

‍

Access the paper here.

Live group demo

See TWAICE Energy Storage Analytics in Action

Sign up for the next live group demo and learn how TWAICE can transform your BESS operations. In just 30 minutes, you’ll get a demo of key features and use cases, and engage with our product experts for a live Q&A.

Join Our Demo
No items found.